Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride

Boukerroui Abdelhamid; Ali Ourari; Mohand Said Ouali

doi:doi:10.11648/j.ajpc.20120101.11

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Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride

Boukerroui Abdelhamid, Ali Ourari, Mohand Said Ouali

Published in American Journal of Physical Chemistry (Volume 1, Issue 1)

Published: 30 December 2012

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Abstract

A raw bentonite, obtained from Maghnia (Western Algerian) was impregnated into 1M ammonium chloride solution and thermally treated in a furnace at 200 °C during one hour. This treatment has improved its removal capacity of copper from aqueous solutions to about 30 %. The performances of the copper adsorption of this new material, after its physicochemical treatment, were evaluated by quantitative analysis on the copper remaining in the solution. The interface phenomena of bentonite- Cu2+ aqueous solution adheres to the Langmuir and Freundlich models. The adsorption energy, calculated by using Dubinin-Radushkevich equation, has proved that the removal of copper with this clay material is an ion exchange process. Nevertheless, the thermal treatment of this clay has inhibited the temperature effect on the retention of copper ions. Thus, the kinetic law governing the copper adsorption described here is following a second order model.

Published in	American Journal of Physical Chemistry (Volume 1, Issue 1)
DOI	10.11648/j.ajpc.20120101.11
Page(s)	1-10
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2012. Published by Science Publishing Group

Keywords

Bentonite Activation, Ammonium Chloride, Removal Of Copper (II)

References

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APA Style

Boukerroui Abdelhamid, Ali Ourari, Mohand Said Ouali. (2012). Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride. American Journal of Physical Chemistry, 1(1), 1-10. https://doi.org/10.11648/j.ajpc.20120101.11

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ACS Style

Boukerroui Abdelhamid; Ali Ourari; Mohand Said Ouali. Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride. Am. J. Phys. Chem. 2012, 1(1), 1-10. doi: 10.11648/j.ajpc.20120101.11

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AMA Style

Boukerroui Abdelhamid, Ali Ourari, Mohand Said Ouali. Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride. Am J Phys Chem. 2012;1(1):1-10. doi: 10.11648/j.ajpc.20120101.11

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@article{10.11648/j.ajpc.20120101.11,
  author = {Boukerroui Abdelhamid and Ali Ourari and Mohand Said Ouali},
  title = {Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride},
  journal = {American Journal of Physical Chemistry},
  volume = {1},
  number = {1},
  pages = {1-10},
  doi = {10.11648/j.ajpc.20120101.11},
  url = {https://doi.org/10.11648/j.ajpc.20120101.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20120101.11},
  abstract = {A raw bentonite, obtained from Maghnia (Western Algerian) was impregnated into 1M ammonium chloride solution and thermally treated in a furnace at 200 °C during one hour. This treatment has improved its removal capacity of copper from aqueous solutions to about 30 %. The performances of the copper adsorption of this new material, after its physicochemical treatment, were evaluated by quantitative analysis on the copper remaining in the solution. The interface phenomena of bentonite- Cu2+ aqueous solution adheres to the Langmuir and Freundlich models. The adsorption energy, calculated by using Dubinin-Radushkevich equation, has proved that the removal of copper with this clay material is an ion exchange process. Nevertheless, the thermal treatment of this clay has inhibited the temperature effect on the retention of copper ions. Thus, the kinetic law governing the copper adsorption described here is following a second order model.},
 year = {2012}
}

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TY  - JOUR
T1  - Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride
AU  - Boukerroui Abdelhamid
AU  - Ali Ourari
AU  - Mohand Said Ouali
Y1  - 2012/12/30
PY  - 2012
N1  - https://doi.org/10.11648/j.ajpc.20120101.11
DO  - 10.11648/j.ajpc.20120101.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 1
EP  - 10
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20120101.11
AB  - A raw bentonite, obtained from Maghnia (Western Algerian) was impregnated into 1M ammonium chloride solution and thermally treated in a furnace at 200 °C during one hour. This treatment has improved its removal capacity of copper from aqueous solutions to about 30 %. The performances of the copper adsorption of this new material, after its physicochemical treatment, were evaluated by quantitative analysis on the copper remaining in the solution. The interface phenomena of bentonite- Cu2+ aqueous solution adheres to the Langmuir and Freundlich models. The adsorption energy, calculated by using Dubinin-Radushkevich equation, has proved that the removal of copper with this clay material is an ion exchange process. Nevertheless, the thermal treatment of this clay has inhibited the temperature effect on the retention of copper ions. Thus, the kinetic law governing the copper adsorption described here is following a second order model.
VL  - 1
IS  - 1
ER  -

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Author Information

Boukerroui Abdelhamid

LTMGP Laboratory, Department of chemistry Faculty of exacts sciences, university of Bejaia Algeria
Ali Ourari

LEIMCR Laboratory, Department of chemistry Faculty of Science and Technology University of Setif Algeria
Mohand Said Ouali

LVM Laboratory, Department of chemistry Faculty of Science and Technology University of Mostaganem, Algeria

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APA Style

Boukerroui Abdelhamid, Ali Ourari, Mohand Said Ouali. (2012). Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride. American Journal of Physical Chemistry, 1(1), 1-10. https://doi.org/10.11648/j.ajpc.20120101.11

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ACS Style

Boukerroui Abdelhamid; Ali Ourari; Mohand Said Ouali. Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride. Am. J. Phys. Chem. 2012, 1(1), 1-10. doi: 10.11648/j.ajpc.20120101.11

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AMA Style

Boukerroui Abdelhamid, Ali Ourari, Mohand Said Ouali. Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride. Am J Phys Chem. 2012;1(1):1-10. doi: 10.11648/j.ajpc.20120101.11

Copy | Download

@article{10.11648/j.ajpc.20120101.11,
  author = {Boukerroui Abdelhamid and Ali Ourari and Mohand Said Ouali},
  title = {Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride},
  journal = {American Journal of Physical Chemistry},
  volume = {1},
  number = {1},
  pages = {1-10},
  doi = {10.11648/j.ajpc.20120101.11},
  url = {https://doi.org/10.11648/j.ajpc.20120101.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20120101.11},
  abstract = {A raw bentonite, obtained from Maghnia (Western Algerian) was impregnated into 1M ammonium chloride solution and thermally treated in a furnace at 200 °C during one hour. This treatment has improved its removal capacity of copper from aqueous solutions to about 30 %. The performances of the copper adsorption of this new material, after its physicochemical treatment, were evaluated by quantitative analysis on the copper remaining in the solution. The interface phenomena of bentonite- Cu2+ aqueous solution adheres to the Langmuir and Freundlich models. The adsorption energy, calculated by using Dubinin-Radushkevich equation, has proved that the removal of copper with this clay material is an ion exchange process. Nevertheless, the thermal treatment of this clay has inhibited the temperature effect on the retention of copper ions. Thus, the kinetic law governing the copper adsorption described here is following a second order model.},
 year = {2012}
}

Copy | Download

TY  - JOUR
T1  - Copper (II) ions removal from aqueous solution using bentonite treated with ammonium chloride
AU  - Boukerroui Abdelhamid
AU  - Ali Ourari
AU  - Mohand Said Ouali
Y1  - 2012/12/30
PY  - 2012
N1  - https://doi.org/10.11648/j.ajpc.20120101.11
DO  - 10.11648/j.ajpc.20120101.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 1
EP  - 10
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20120101.11
AB  - A raw bentonite, obtained from Maghnia (Western Algerian) was impregnated into 1M ammonium chloride solution and thermally treated in a furnace at 200 °C during one hour. This treatment has improved its removal capacity of copper from aqueous solutions to about 30 %. The performances of the copper adsorption of this new material, after its physicochemical treatment, were evaluated by quantitative analysis on the copper remaining in the solution. The interface phenomena of bentonite- Cu2+ aqueous solution adheres to the Langmuir and Freundlich models. The adsorption energy, calculated by using Dubinin-Radushkevich equation, has proved that the removal of copper with this clay material is an ion exchange process. Nevertheless, the thermal treatment of this clay has inhibited the temperature effect on the retention of copper ions. Thus, the kinetic law governing the copper adsorption described here is following a second order model.
VL  - 1
IS  - 1
ER  -

Copy | Download