Synthesis of a Biobased Antioxidant Additive for Diesel Fuel

Chikh Sabrina; Pemanos Yelda Bakoz; Zourane Tinhinane; Hamada Boudjema

doi:doi:10.11648/j.ajac.20140201.13

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Synthesis of a Biobased Antioxidant Additive for Diesel Fuel

Chikh Sabrina, Pemanos Yelda Bakoz, Zourane Tinhinane, Hamada Boudjema

Published in American Journal of Applied Chemistry (Volume 2, Issue 1)

Received: 5 February 2014 Published: 10 March 2014

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Abstract

In this study, our objective is to synthesize a biobased antioxidant additive for Diesel fuel during the storage. Our choice was made particularly on the olive oil as raw material because of its oleic acid content which is more to 75%. The processes involved were epoxidation of oleic acid of the olive oil, opening of the oxirane ring, and esterification. The structures of the products were confirmed by FTIR. To test the effectiveness of our biobased antioxidant additive, we carried out Accelerated Oxidation Test – AOT on diesel without additive (blank) and diesel with additive with various concentrations: 2000,4000 and 6000 ppm. The oxidative degradation of diesel with or without antioxidants was investigated by UV-visible spectroscopy was used to monitor the changes using peroxide value. A remarkable stability of diesel with antioxidant additive comparing with the blank confirms the inhibition of the oxidation phoneme and thus of the good efficiency of antioxidant additive from the optimal concentration of 2000ppm.

Published in	American Journal of Applied Chemistry (Volume 2, Issue 1)
DOI	10.11648/j.ajac.20140201.13
Page(s)	10-14
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Biobased Additive, Antioxidant, Diesel Fuel, Peroxide Value, Accelerated Oxidation Test

References

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[3]	M.Eissen,J.Metzger,E.Schmidt,U. Schneidewind, "10 years after Rio - Concepts on the contribution of chemistry to a sustainable development, Angew". Chem. Int. Ed (2002) 41, 414-436.
[4]	M.Genas, Rilsan (Polyamid 11), "Synthese and Eigenschaften, Angewandte Chemie", (1962)74,535-540.
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[6]	D.Chaithongdee,J.Chutmanop,P.Srinophakun, "Effect of Antioxidants and Additives on the Oxidation Stability of Jatropha Biodiesel". Kasetsart Journal – Natural Science (2010) 44, 243-50.
[7]	M.L.A.Tavares, N.Queiroz,I.M.G .Santos, A. L.Souza,E. H. S.Cavalcanti, A. K. D. Barros, R.Rosenhaim, L. E. B.Soledade, A. G. Souza, "Sunflower Biodiesel. Use of P-DSC in the Evaluation of Antioxidant Efficiency". Journal of Thermal Analysis and Calorimetry (2011) 106(2), 575-9.
[8]	L. R.Almeida, A. L.Silva, F. H. N.Souza, A. A. Hidalgo, M. L.Vega, H. N.Cunha, M. A. S. Rios, "Evaluation of Antioxidant Potentiality of Compounds Derived from Biomass for Application in Biodiesel from Soybean Oil", Química no Brasil, (2011).
[9]	H. N. Fernando Souza, R.de Almeida Layane, C. L. Batista Francisco Samuel, Alexsandra de S. Rios Maria, "UV-Visible Spectroscopy Study of Oxidative Degradation of Sunflower Biodiesel",CSCanada Energy Science and Technology Vol. 2, (2011), pp. 56-61.
[10]	J.Salimon, N.Salih, E.Yousif, "Chemically modified biolubricant basestocks from epoxidized oleic acid: Improved low temperature properties and oxidative stability",Journal of Saudi Chemical Society (2011) 15, 195–201.
[11]	Tayde Saurabh., M.b.Patnaik, S.L. Bhagt, V.C. Renge, "Epoxidation of vegetable oils", International journal of advanced engineering technology, a review (2011) 0976-3945.
[12]	Z.S.Petrovic, A. Zlatanic , C.C. Lava , S. Sinadinovicfise , "Epoxidation of soya bean oil in toluene with peroxoacetic acid and peroxoformic acids-kinetics and side reactions". European Journal of Lipid Science and Technology (2002). 104(5):293-299.
[13]	S.F.Snezana, J.Milovan, S.P.Zoran. "Kinetics of in situ Epoxidation of Soybean Oil in Bulk Catalyzed by Ion Exchange Resin" JAOCS, Vol1, (2001). 78, no. 7
[14]	N. Salih, J. Salimon, E.Youcef, "Synthesis of oleic acid based esters as potential basestock for biolubricant production". Turkish J. Eng. Env. Sci. (2011) 35, 115 – 123.

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APA Style

Chikh Sabrina, Pemanos Yelda Bakoz, Zourane Tinhinane, Hamada Boudjema. (2014). Synthesis of a Biobased Antioxidant Additive for Diesel Fuel. American Journal of Applied Chemistry, 2(1), 10-14. https://doi.org/10.11648/j.ajac.20140201.13

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ACS Style

Chikh Sabrina; Pemanos Yelda Bakoz; Zourane Tinhinane; Hamada Boudjema. Synthesis of a Biobased Antioxidant Additive for Diesel Fuel. Am. J. Appl. Chem. 2014, 2(1), 10-14. doi: 10.11648/j.ajac.20140201.13

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AMA Style

Chikh Sabrina, Pemanos Yelda Bakoz, Zourane Tinhinane, Hamada Boudjema. Synthesis of a Biobased Antioxidant Additive for Diesel Fuel. Am J Appl Chem. 2014;2(1):10-14. doi: 10.11648/j.ajac.20140201.13

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@article{10.11648/j.ajac.20140201.13,
  author = {Chikh Sabrina and Pemanos Yelda Bakoz and Zourane Tinhinane and Hamada Boudjema},
  title = {Synthesis of a Biobased Antioxidant Additive for Diesel Fuel},
  journal = {American Journal of Applied Chemistry},
  volume = {2},
  number = {1},
  pages = {10-14},
  doi = {10.11648/j.ajac.20140201.13},
  url = {https://doi.org/10.11648/j.ajac.20140201.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20140201.13},
  abstract = {In this study, our objective is to synthesize a biobased antioxidant additive for Diesel fuel during the storage. Our choice was made particularly on the olive oil as raw material because of its oleic acid content which is more to 75%. The processes involved were epoxidation of oleic acid of the olive oil, opening of the oxirane ring, and esterification. The structures of the products were confirmed by FTIR. To test the effectiveness of our biobased antioxidant additive, we carried out Accelerated Oxidation Test – AOT on diesel without additive (blank) and diesel with additive with various concentrations: 2000,4000 and 6000 ppm. The oxidative degradation of diesel with or without antioxidants was investigated by UV-visible spectroscopy was used to monitor the changes using peroxide value. A remarkable stability of diesel with antioxidant additive comparing with the blank confirms the inhibition of the oxidation phoneme and thus of the good efficiency of antioxidant additive from the optimal concentration of 2000ppm.},
 year = {2014}
}

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TY  - JOUR
T1  - Synthesis of a Biobased Antioxidant Additive for Diesel Fuel
AU  - Chikh Sabrina
AU  - Pemanos Yelda Bakoz
AU  - Zourane Tinhinane
AU  - Hamada Boudjema
Y1  - 2014/03/10
PY  - 2014
N1  - https://doi.org/10.11648/j.ajac.20140201.13
DO  - 10.11648/j.ajac.20140201.13
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 10
EP  - 14
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20140201.13
AB  - In this study, our objective is to synthesize a biobased antioxidant additive for Diesel fuel during the storage. Our choice was made particularly on the olive oil as raw material because of its oleic acid content which is more to 75%. The processes involved were epoxidation of oleic acid of the olive oil, opening of the oxirane ring, and esterification. The structures of the products were confirmed by FTIR. To test the effectiveness of our biobased antioxidant additive, we carried out Accelerated Oxidation Test – AOT on diesel without additive (blank) and diesel with additive with various concentrations: 2000,4000 and 6000 ppm. The oxidative degradation of diesel with or without antioxidants was investigated by UV-visible spectroscopy was used to monitor the changes using peroxide value. A remarkable stability of diesel with antioxidant additive comparing with the blank confirms the inhibition of the oxidation phoneme and thus of the good efficiency of antioxidant additive from the optimal concentration of 2000ppm.
VL  - 2
IS  - 1
ER  -

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Author Information

Chikh Sabrina

Laboratory of Petrochemical synthesis, Faculty of Hydrocarbons and Chemistry, University M’hamed Bouguara-Boumerdes, Algeria
Pemanos Yelda Bakoz

Depatment of Chemistry, College of Science, University of ZaKho, Kurdistan Rigion, Iraq
Zourane Tinhinane

Laboratory of Petrochemical synthesis, Faculty of Hydrocarbons and Chemistry, University M’hamed Bouguara-Boumerdes, Algeria
Hamada Boudjema

Laboratory of Petrochemical synthesis, Faculty of Hydrocarbons and Chemistry, University M’hamed Bouguara-Boumerdes, Algeria

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Plain Text BibTeX RIS

APA Style

Chikh Sabrina, Pemanos Yelda Bakoz, Zourane Tinhinane, Hamada Boudjema. (2014). Synthesis of a Biobased Antioxidant Additive for Diesel Fuel. American Journal of Applied Chemistry, 2(1), 10-14. https://doi.org/10.11648/j.ajac.20140201.13

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ACS Style

Chikh Sabrina; Pemanos Yelda Bakoz; Zourane Tinhinane; Hamada Boudjema. Synthesis of a Biobased Antioxidant Additive for Diesel Fuel. Am. J. Appl. Chem. 2014, 2(1), 10-14. doi: 10.11648/j.ajac.20140201.13

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AMA Style

Chikh Sabrina, Pemanos Yelda Bakoz, Zourane Tinhinane, Hamada Boudjema. Synthesis of a Biobased Antioxidant Additive for Diesel Fuel. Am J Appl Chem. 2014;2(1):10-14. doi: 10.11648/j.ajac.20140201.13

Copy | Download

@article{10.11648/j.ajac.20140201.13,
  author = {Chikh Sabrina and Pemanos Yelda Bakoz and Zourane Tinhinane and Hamada Boudjema},
  title = {Synthesis of a Biobased Antioxidant Additive for Diesel Fuel},
  journal = {American Journal of Applied Chemistry},
  volume = {2},
  number = {1},
  pages = {10-14},
  doi = {10.11648/j.ajac.20140201.13},
  url = {https://doi.org/10.11648/j.ajac.20140201.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20140201.13},
  abstract = {In this study, our objective is to synthesize a biobased antioxidant additive for Diesel fuel during the storage. Our choice was made particularly on the olive oil as raw material because of its oleic acid content which is more to 75%. The processes involved were epoxidation of oleic acid of the olive oil, opening of the oxirane ring, and esterification. The structures of the products were confirmed by FTIR. To test the effectiveness of our biobased antioxidant additive, we carried out Accelerated Oxidation Test – AOT on diesel without additive (blank) and diesel with additive with various concentrations: 2000,4000 and 6000 ppm. The oxidative degradation of diesel with or without antioxidants was investigated by UV-visible spectroscopy was used to monitor the changes using peroxide value. A remarkable stability of diesel with antioxidant additive comparing with the blank confirms the inhibition of the oxidation phoneme and thus of the good efficiency of antioxidant additive from the optimal concentration of 2000ppm.},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Synthesis of a Biobased Antioxidant Additive for Diesel Fuel
AU  - Chikh Sabrina
AU  - Pemanos Yelda Bakoz
AU  - Zourane Tinhinane
AU  - Hamada Boudjema
Y1  - 2014/03/10
PY  - 2014
N1  - https://doi.org/10.11648/j.ajac.20140201.13
DO  - 10.11648/j.ajac.20140201.13
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 10
EP  - 14
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20140201.13
AB  - In this study, our objective is to synthesize a biobased antioxidant additive for Diesel fuel during the storage. Our choice was made particularly on the olive oil as raw material because of its oleic acid content which is more to 75%. The processes involved were epoxidation of oleic acid of the olive oil, opening of the oxirane ring, and esterification. The structures of the products were confirmed by FTIR. To test the effectiveness of our biobased antioxidant additive, we carried out Accelerated Oxidation Test – AOT on diesel without additive (blank) and diesel with additive with various concentrations: 2000,4000 and 6000 ppm. The oxidative degradation of diesel with or without antioxidants was investigated by UV-visible spectroscopy was used to monitor the changes using peroxide value. A remarkable stability of diesel with antioxidant additive comparing with the blank confirms the inhibition of the oxidation phoneme and thus of the good efficiency of antioxidant additive from the optimal concentration of 2000ppm.
VL  - 2
IS  - 1
ER  -

Copy | Download