Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattanaik; Anita Routaray; Prasanta Rath; Tungabidya Maharana

doi:doi:10.11648/j.ajac.20130102.13

| Peer-Reviewed

Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattanaik, Anita Routaray, Prasanta Rath, Tungabidya Maharana

Published in American Journal of Applied Chemistry (Volume 1, Issue 2)

Received: 25 May 2013 Published: 10 July 2013

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveals that iron(III) complex of 3-MHBdMBn Schiff base is octahedral in geometry, whereas, cobalt(II) ions complexes is square planar. Complexation of metal ions increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activities of metal complexes towards the oxidation of phenol are investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-M is dramatically affected by the polymer support over 3-MHBdMBn-M and iron complexes have greater activity than the cobalt analogue.

Published in	American Journal of Applied Chemistry (Volume 1, Issue 2)
DOI	10.11648/j.ajac.20130102.13
Page(s)	28-36
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Schiff Base, Polymer Support, Catalysis, Metal Complexes, Phenol, Oxidation

References

[1]	J. Tong, Y. Zhang, Z. Li, C. Xia. "Highly effective catalysts of natural polymer supported salophen Mn(III) complexes for aerobic oxidation of cyclohexane." J. Mol. Catal. A: Chem. 2006; 249: 47–52.
[2]	K. C. Gupta, A. K. Sutar, "Catalytic activities of Schiff base transition metal complexes." Coord. Chem. Rev. 2008; 252(12-14):1420-1450.
[3]	S. Tangestaninejad, M. H. Habibi, V. Mirkhani, M. Moghadam, G. Grivani, "Simple preparation of some reusable and efficient polymer supported tungsten carbonyl catalysts and clean epoxidation of cis-cyclooctene in the presence of H2O2." J. Mol. Catal. A: Chem. 2006; 255: 249–253.
[4]	A. K. Sutar, T. Maharana, S. Dutta, Chi-Tien Chen, Chu-Chieh Lin, "Ring-opening polymerization by lithium catalysts: an overview." Chem. Soc. Rev., 2010, 39, 1724–1746.
[5]	Y. Nakayama, H. Bando, Y. Sonobe, T. Fuzita, "Olefin polymeri- zation behavior of bis (phenoxy-imine) Zr, Ti and V com- plexes with MgCl2-based cocatalysts." J. Mol. Catal. A: Chem. 2004; 213: 141–1150.
[6]	K. C. Gupta, A. K. Sutar, C. C. Lin, "Polymer supported Schiff base complexes in oxidation reactions." Coord. Chem. Rev. 2009; 253:1926–1946.
[7]	A. Akelah, A. Rehab, ER. Kenawy, MS. Zeid, MS. Abou, "Catalytic activity of polymer-montmorillonites in chemical reactions." J. Appl. Polym. Sci. 2006; 101: 1121–1129.
[8]	R. S. Drago, J. Gaul, A. Zombeck, D. K. Straub, "Preparation and catalytic oxidizing potential of polymer supported chelating amine and Schiff base complexes." J. Am. Chem. Soc. 1980; 102:1033–1038.
[9]	L. Canali, E. Cowan, C. L. Gibson, D. C. Sherrington, H. Delueze, "Remarkable matrix effect in polymer supported Jacobson’s alkene epoxidation catalysts." Chem. Commun. 1998; 23: 2501–2508.
[10]	M. Salavati-Niasari, P. Salemi, F. Davar, "Oxidation of cyclo- hexene with tert- butylhydroperoxide and hydrogen per- oxide catalyzed by Cu(II), Ni(II),Co(II), and Mn(II) complexes of N,N’-bis(a-methylsalicylidene) -2,2-dimethyl -2,2-dimethylpropane-1, 3-diamaine, supported on alumina." J. Mol. Catal. A: Chem. 2005; 238: 215–222.
[11]	F. AlObaidi, Z. Ye, S. Zhu, "Ethylene polymerization with silica-supported nickel-diimine catalyst: effect of support and polymerization conditions on catalyst activity and polymer properties." Macromol. Chem. Phys. 2003; 204: 1653–1659.
[12]	A. Casagrande, T. Tavares, M. C. A Kuhn, O. L Casagrande, HZ S. Joao, T. Teranishi "Tris(pyrazolyl) borate imido vanadium (V) compound immobilized on inorganic supports and its use in ethylene polymerization." J. Mol. Catal. A: Chem. 2004; 212:267–275.
[13]	R-M. Wang, Z-L. Zhang, J-F. Lou, Y-P. Wang, P-F. Song, C-G. Xia. "Preparation and catalytic oxidation properties of inor- ganic polymer encapsulated metal complexes." Polym. Adv. Technol. 2004;15: 48–51.
[14]	A. Fuerte, M. Iglesias, F. Sanchez, A..Corma "Chiral dioxomo- lybdenum(VI) and oxovanadium(V) complexes anchored on modified USY-zeolite and mesoporous MCM-41 as solid selective catalyst for oxidation of sulfides or sulfones." J. Mol. Catal A: Chem. 2004; 211: 227–235.
[15]	B. Daniela, SF. Chiarello, JH. Zimnoch dos Santos. "Effect of MAO silica surface loading on (nBuCp)2ZeCl2 anchoring on catalyst actvity and on polymer properties." Appl. Catal. A: Gen. 2004; 261: 57–67.
[16]	K. C. Gupta, A. K. Sutar, "Polymer supported catalysts for oxidation of phenol and cyclohexene using hydrogen peroxide as oxidant." J. Mol. Catal. A: Chem. 2008; 280:173-185.
[17]	I. Owsik, BN. Kolarz, J. Jezierska, "Oxidation of 2,6-ditert- butylphenols to diphenoquinones catalyzed by sciff base-Cu(II) systems immobolized on polymer support." J. Catal. Lett. 2006; 107: 197–203.
[18]	C. Wang, W. Xin, X. Fu, Y. Zhang, Y. Yang, "Studies on catalytic polarographic hydrogen wave in iridium(IV)-cysteine- hydrochloric acid and its application." Fenxi Huaxue 1992; 20: 368–372.
[19]	K. C. Gupta, A. K. Sutar, "Polymer anchored Schiff base complexes of transition metal ions and their catalytic activities in oxidation of phenol." J. Mol. Catal. A: Chem. 2007; 272: 64-74.
[20]	K. C. Gupta, A. K. Sutar, "Polymer supported Schiff base complexes of Iron(III), Cobalt(II) and Nickel(II) ions and their catalytic activity in oxidation of phenol and cyclohexane." J. Macro mole. Sci. Part A: Pure and Appl. Chem. 2007; 44:1171-118535.
[21]	Vogel AI. Textbook of Practical Organic Chemistry, 1978.

Cite This Article

Plain Text BibTeX RIS

APA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattanaik, Anita Routaray, Prasanta Rath, et al. (2013). Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. American Journal of Applied Chemistry, 1(2), 28-36. https://doi.org/10.11648/j.ajac.20130102.13

Copy | Download

ACS Style

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattanaik; Anita Routaray; Prasanta Rath, et al. Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. Am. J. Appl. Chem. 2013, 1(2), 28-36. doi: 10.11648/j.ajac.20130102.13

Copy | Download

AMA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattanaik, Anita Routaray, Prasanta Rath, et al. Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. Am J Appl Chem. 2013;1(2):28-36. doi: 10.11648/j.ajac.20130102.13

Copy | Download

@article{10.11648/j.ajac.20130102.13,
  author = {Alekha Kumar Sutar and Yasobanta Das and Sasmita Pattanaik and Anita Routaray and Prasanta Rath and Tungabidya Maharana},
  title = {Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {2},
  pages = {28-36},
  doi = {10.11648/j.ajac.20130102.13},
  url = {https://doi.org/10.11648/j.ajac.20130102.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130102.13},
  abstract = {The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveals that iron(III) complex of  3-MHBdMBn Schiff base is octahedral in geometry, whereas, cobalt(II) ions complexes is square planar. Complexation of metal ions increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activities of metal complexes towards the oxidation of phenol are investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-M is dramatically affected by the polymer support over 3-MHBdMBn-M and iron complexes have greater activity than the cobalt analogue.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands
AU  - Alekha Kumar Sutar
AU  - Yasobanta Das
AU  - Sasmita Pattanaik
AU  - Anita Routaray
AU  - Prasanta Rath
AU  - Tungabidya Maharana
Y1  - 2013/07/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130102.13
DO  - 10.11648/j.ajac.20130102.13
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 28
EP  - 36
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130102.13
AB  - The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveals that iron(III) complex of  3-MHBdMBn Schiff base is octahedral in geometry, whereas, cobalt(II) ions complexes is square planar. Complexation of metal ions increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activities of metal complexes towards the oxidation of phenol are investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-M is dramatically affected by the polymer support over 3-MHBdMBn-M and iron complexes have greater activity than the cobalt analogue.
VL  - 1
IS  - 2
ER  -

Copy | Download

Author Information

Alekha Kumar Sutar

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Yasobanta Das

School of Applied Sciences (Chemistry), KIIT University, Bhubaneswar, Odisha, India
Sasmita Pattanaik

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Anita Routaray

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Prasanta Rath

School of Applied Sciences (Chemistry), KIIT University, Bhubaneswar, Odisha, India
Tungabidya Maharana

Department of Chemistry, National Institute of Technology, Raipur, India

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattanaik, Anita Routaray, Prasanta Rath, et al. (2013). Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. American Journal of Applied Chemistry, 1(2), 28-36. https://doi.org/10.11648/j.ajac.20130102.13

Copy | Download

ACS Style

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattanaik; Anita Routaray; Prasanta Rath, et al. Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. Am. J. Appl. Chem. 2013, 1(2), 28-36. doi: 10.11648/j.ajac.20130102.13

Copy | Download

AMA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattanaik, Anita Routaray, Prasanta Rath, et al. Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. Am J Appl Chem. 2013;1(2):28-36. doi: 10.11648/j.ajac.20130102.13

Copy | Download

@article{10.11648/j.ajac.20130102.13,
  author = {Alekha Kumar Sutar and Yasobanta Das and Sasmita Pattanaik and Anita Routaray and Prasanta Rath and Tungabidya Maharana},
  title = {Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {2},
  pages = {28-36},
  doi = {10.11648/j.ajac.20130102.13},
  url = {https://doi.org/10.11648/j.ajac.20130102.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130102.13},
  abstract = {The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveals that iron(III) complex of  3-MHBdMBn Schiff base is octahedral in geometry, whereas, cobalt(II) ions complexes is square planar. Complexation of metal ions increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activities of metal complexes towards the oxidation of phenol are investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-M is dramatically affected by the polymer support over 3-MHBdMBn-M and iron complexes have greater activity than the cobalt analogue.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands
AU  - Alekha Kumar Sutar
AU  - Yasobanta Das
AU  - Sasmita Pattanaik
AU  - Anita Routaray
AU  - Prasanta Rath
AU  - Tungabidya Maharana
Y1  - 2013/07/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130102.13
DO  - 10.11648/j.ajac.20130102.13
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 28
EP  - 36
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130102.13
AB  - The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveals that iron(III) complex of  3-MHBdMBn Schiff base is octahedral in geometry, whereas, cobalt(II) ions complexes is square planar. Complexation of metal ions increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activities of metal complexes towards the oxidation of phenol are investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-M is dramatically affected by the polymer support over 3-MHBdMBn-M and iron complexes have greater activity than the cobalt analogue.
VL  - 1
IS  - 2
ER  -

Copy | Download